Schema.org is a taxonomy of types (Product, Organization, Person, Article, FAQPage…) and properties (name, price, description, sameAs, author…). It's the lingua franca AI models use to understand what a page is about beyond its prose.
You don't pick Schema.org — you emit it. The preferred wire format is JSON-LD embedded in the document head. Most AI retrievers parse JSON-LD before parsing the body.